Pyrite form of group-14 element pernitrides synthesized at high pressure and high temperature.
نویسندگان
چکیده
The chemical reaction of group-14 elements with molecular nitrogen at pressures above 60 GPa successfully leads to the formation of pyrite-type pernitrides. These new crystalline group-14 elemental pernitrides were found to show a bulk modulus higher than the other known group-14 elemental nitrides. Our results offer significant new progress in the solid-state chemistry of nitrides.
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عنوان ژورنال:
- Dalton transactions
دوره 46 30 شماره
صفحات -
تاریخ انتشار 2017